RE: A little chemistry

From: Vandergraaf, Chuck (vandergraaft@aecl.ca)
Date: Wed Jan 31 2001 - 18:05:08 EST

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    Al,

    My organic chemistry is a bit rusty, to say the least. Is it possible that
    the bacon grease was oxidized at the high temperatures and that the double
    bonds had been broken?

    Chuck (aboc: anything but organic chemist) Vandergraaf

    -----Original Message-----
    From: Mccarrick Alan D CRPH [mailto:MccarrickAD@nswccd.navy.mil]
    Sent: Wednesday January 31, 2001 8:10 AM
    To: 'ASA List'
    Subject: A little chemistry

    This is somewhat unusual but here goes:

    We did a chemistry lab to measure the relative number of double bonds in
    common fats and oils - iodine will react with the double bonds and the color
    will disappear. The amount of iodine added to make a permanent color change
    is a direct measure of the unsaturation of the oil. We used several common
    oils, and butter (mostly saturated) and left over bacon grease (gross) -
    that I assumed would also be saturated. The iodine tests with the oils
    worked well, but the bacon grease should the HIGHEST amount of unsaturated
    bonds. Why did this happen ? The grease was the only fat that had been
    cooked at high temperature.

    Any suggestions ?

    As an aside - we also made soaps with them - only the butter and grease
    produced foamy soaps - oils didn't.

    Al McCarrick



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